化工热力学-(英文版)_PDF下载[81MB-百度云]于志家

本书特色

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本书适合48学时的教学计划。重点侧重于运用热力学基本原理与定律解决化工过程开发、设计与运行中的实际问题。教材内容主要涵盖：流体的p—v—t关系，流体的热力学性质，热力学基本定律及其应用，压缩、膨胀、蒸汽动力循环及制冷循环，化工过程的热力学分析，溶液的热力学及流体相平衡。

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作者简介

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于志家，大连理工大学化学工程系，化学工程系副主任，副教授，长期从事化学工程基础、化工传递、单元操作、多相流动与化工热力学等方面的科学研究与教学。负责完成国家自然科学基金项目2项，辽宁省自然科学基金项目2项，完成企业工程设计等多项，对化工热力学的基础理论及其在相关研究与工程实际中的应用有深层次的理解与心得。
　　主讲本科生《化工热力学》与《化工计算》课程，双语教学，获大连理工大学优秀课程与教学质量优秀奖。主讲研究生专业课《多相流传递》。

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chapter 1introduction1.1the scope of chemical engineering thermodynamics1.2system and surroundings1.3the chemical state and fluid properties1.4the first law of thermodynamics1.4.1the first law of thermodynamics for controlled mass system1.4.2the first law of thermodynamics for controlled volume system1.5the second law of thermodynamics1.5.1the upper limit for the conversion of heat into work1.5.2entropy1.5.3mathematical statement of the second lawproblems16chapter 2volumetric properties of fluids2.1p.v.t behavior of pure substances2.2the equations of state(eos)of fluid2.2.1the eos of ideal gas2.2.2virial equations of state2.3cubic equations of state2.3.1the van der waals equation of state2.3.2the redlich.kwong(r.k)equation of state2.3.3the soave.redlich.kwong(srk)equation of state2.3.4the peng.robinson(p.r)equation of state2.3.5a generic cubic equation of state2.4generalized correlations of gases2.4.1theorem of corresponding states2.4.2generalized cubic eos2.4.3two.parameter theorem of corresponding states2.4.4three.parameter theorem of corresponding states2.4.5generalized correlations of the second virial coefficient2.5liquid & liquid.like roots of the generic cubic eos2.6generalized correlations for liquidsproblems47chapter 3thermodynamic properties of fluids3.1property relations for homogenous phases3.2calculations of enthalpy and entropy3.3residual properties3.4residual properties by eos3.5calculations of liquid enthalpy and entropy3.6generalized property correlations for gases3.6.1generalized compressibility factor z for residual enthalpy and residual entropy3.6.2generalized second virial coefficient for residual enthalpy and residual entropy3.7thermodynamic diagrams3.8tables of thermodynamic properties3.9t.s diagrams3.9.1heating and cooling processes at isopiestic pressure3.9.2throttling expansion processes3.9.3isentropic expansion or compression processes3.10p.h diagrams3.11h.s diagramsproblems75chapter 4thermodynamic properties of mixtures4.1the mixing rules4.2the calculations of vm,mix and zmix4.2.1amagat’s law(part volume law)combined with z graphs4.2.2eos for a mixture of real gases4.3the calculations of hr and sr4.3.1the calculations of hr and sr by eos4.3.2the calculations of hr and sr by generalized correlation graphsproblems90chapter 5solution thermodynamics5.1property relations for open systems and chemical potential5.2partial properties5.3fugacity and fugacity coefficient5.3.1fugacity calculations for pure gases5.3.2fugacity calculations for pure liquids5.3.3fugacity calculations for species in solution5.3.4application of microsoft excel in the thermodynamic property calculations5.4the ideal solution and standard state5.5excess properties and property change in mixing5.5.1excess properties5.5.2property change in mixing5.5.3h.x graph5.6activity and activity coefficient5.6.1the wohl type equations5.6.2the gamma equation based on local composition5.6.3the uniquac and unifac modelproblems136chapter 6phase equilibrium6.1the criterion of phases equilibrium6.2vapor.liquid equilibrium6.2.1vle under low pressures6.2.2vle under moderate pressures6.2.3vle under high pressures6.3gas.liquid equilibrium6.4liquid.liquid equilibrium6.4.1lle phase diagrams6.4.2the stability of liquid solution6.4.3lle calculations6.5vapor.liquid.liquid equilibrium (vlle)problems178chapter 7thermodynamics of flow process7.1conservation of mass7.2conservation of energy7.3entropy balance7.3.1concept of entropy7.3.2entropy balance7.4processes analyzed by thermodynamics methods7.4.1fluid flowing7.4.2compression process7.4.3expansion process7.4.4throttling processproblems209chapter 8thermodynamics cycle8.1carnot.cycle and its anticlockwise cycle8.2rankine.cycle & steam power plant8.2.1improving of the carnot engine8.2.2improving of the rankine engine8.3vapor compression refrigeration cycle8.4absorption refrigeration8.5heat pump8.5.1a brief historical development of heat pumps8.5.2vapor compression hp8.5.3absorption heat pumpproblems242chapter 9thermodynamic analysis of processes9.1ideal work9.1.1non.flowing process9.1.2steady.state flow process9.2lost work9.3typical problems9.3.1tube flow9.3.2heat transfer9.4 energy optimizationproblems252appendixappendix aconversion factors and values of the gas constantappendix bproperties of pure speciesappendix cheat capacities and property changes of formationappendix dthe lee/kesler generalized correlation tablesappendix esteam tableslist of symbolsselected glossary in chemical engineering thermodynamics with chinese translationreferences