微纳米结构的导电聚合物_PDF下载[52MB-百度云]万梅香

节选

[

《微纳米结构的导电聚合物》适合高校和科研院所的化学、化工、物理及材料专业的研究人员、教师和研究生阅读参考。导电聚合物打破了聚合物为绝缘体的传统观念，因而被称为“第四代聚合物”。它既具有金属和半导体的导电特性，又保留了聚合物的轻质、柔性和可加工的特色。这种材料在光电子器件、传感技术、分子电子学和纳米器件以及驱动器件等方面具有潜在的应用前景。《微纳米结构的导电聚合物》比较完整、系统地介绍了导电聚合物的缘起、掺杂与导电机制、结构与性能、技术应用前景以及研究进展，特别介绍了作者采用无模板自组装方法在微纳米结构的导电聚合物的研究及其应用方面的学术贡献。《微纳米结构的导电聚合物》的内容分为5章：第1章，导论；第2章，优异的导电聚苯胺；第3章，导电聚合物的物理特性及其应用；第4章，导电聚合物的微纳米结构；第5章，无模板法自组装导电聚合物的微纳米结构。为了便于读者阅读，作者还特别给出了名词解释。

]

本书特色

[

《微纳米结构的导电聚合物》由清华大学出版社出版。
Conducting Polymers with Micro or Nanometer Structure describes a topicdiscovered by three winners of the Nobel Prize in Chemistry in 2000: AlanJ. Heeger, University of California at Santa Barbara, Alan G. MacDiarmid atthe University of Pennsylvania, and Hideki Shirakawa at the University ofTsukuba. Since then, the unique properties of conducting polymers have ledto promising applications in functional materials and technologies. The bookfirst briefly summarizes the main concepts of conducting polymers beforeintroducing micro/nanostructured conducting polymers dealing with theirsynthesis, structural characterizations, formation mechanisms, physical and chemical properties, and potential applications in nanomaterials andnanotechnology. The book is intended for researchers in the related fieldsof chemistry, physics, materials, nanomaterials and nanodevices. MeixiangWan is a professor at the Institute .of Chemistry, Chinese Academy ofSciences, Beijing.

]

内容简介

[

简介
　　导电聚合物打破了聚合物为绝缘体的传统观念，因而被称为“第四代聚合物”。它既具有金属和半导体的导电特性，又保留了聚合物的轻质、柔性和可加工的特色。这种材料在光电子器件、传感技术、分子电子学和纳米器件以及驱动器件等方面具有潜在的应用前景。本书比较完整、系统地介绍了导电聚合物的缘起、掺杂与导电机制、结构与性能、技术应用前景以及研究进展，特别介绍了作者采用无模板自组装方法在微纳米结构的导电聚合物的研究及其应用方面的学术贡献。本书的内容分为5章：第1章，导论；第2章，优异的导电聚苯胺；第3章，导电聚合物的物理特性及其应用；第4章，导电聚合物的微纳米结构；第5章，无模板法自组装导电聚合物的微纳米结构。为了便于读者阅读，作者还特别给出了名词解释。　　本书适合高校和科研院所的化学、化工、物理及材料专业的研究人员、教师和研究生阅读参考。

]

Chapter I Introduction of Conducting Polymers1.1 Discovery of Conducting Polymers1.2 Structural Characteristics and Doping Concept1.3 Charge Carriers and Conducting MechanismReferencesChapter 2 Polyaniline as A Promising Conducting Polymer2.1 Molecular Structure and Proton Doping2.2 Synthesis Method2.2.1 Chemical Method2.2.2 Electro-Chemical Method2.2.3 Mechano-Chemical Route2.3 Physical Properties .2.3.1 Nonlinear Optical (NLO)2.3.2 Electrical and Charge Transport Properties2.3.3 Magnetic Properties2.3.4 Other Properties2.4 Solubility and Processability2.4.1 Solubility2.4.2 ProcessabilityReferencesChapter 3 Physical Properties and Associated Applications of Conducting Polymers3.1 Electronic Devices3.1.1 Light Emitting Diodes (LEDs)3.1.2 Solar Cells3.2 EMI Shielding and Microwave Absorbing Materials3.2.1 EMI Shielding Materials3.2.2 Microwave Absorption Materials (Stealth Materials)3.3 Rechargeable Batteries and Supercapacitors3.3.1 Rechargeable Batteries3.3.2 Supercapacitors3.4 Sensors3.5 Electrochromic Devices and Artificial Muscles3.5.1 Electrochromic Devices3.5.2 Conducting Polymer-Based Artificial Muscles3.6 Others3.6.1 Corrosion Materials3.6.2 Electrostatic Dissipation Materials3.6.3 Separated Membrane3.6.4 Conducting TextilesReferencesChapter 4 Conducting Polymer Nanostructures4.1 Synthetic Method and Formation Mechanism4.1.1 Hard Template Method 4.1.2 Soft Template Method4.1.3 Other Methods4.1.4 PEDOT Nanostructures4.2 Composite Nanostructures4.2.1 Metal-Conducting Polymer Composite Nanostructures4.2.2 Conducting Polymer/Carbon Nanotube Composites4.2.3 Core-Shell Composites4.2.4 Chiral and Biological Composite Nanostructures4.2.5 Inorganic Oxide Nano-Crystals and CP Composites4.3 Physical Properties and Potential Application4.3.1 Electrical and Transport Properties4.3.2 Potential Applications4.3.3 Nano-arrays or Nano-patents ReferencesChapter 5 Template-Free Method to Conducting Polymer MicrofNanostructures5.1 Template-Free Method5.1.1 Discovery of Template-Free Method5.1.2 Universality of Template-Free Method5.1.3 Controllability of Morphology and Diameter by Template-Free Method5.1.4 Self-Assembly Mechanism of Micro/Nanostructures by A Template-Free Method5.2 Multi-Functionality of Micro/Nanostmctures Based on Template-Free Method5.2.1 Processing Composite Nanostructures5.2.2 PPy-CNT Composite Nanostructures5.2.3 Electro-Magnetic Functional Micro/Nanostructures5.2.4 Electro-Optic Micro/Nanostructures5.2.5 Super-Hydrophobic 3D-Microstructures Assembled from 1D-Nanofibers5.3 Mono-Dispersed and Oriented Micro/Nanostructures5.3. I Template-Free Method Combined with A1203 Template for Oriented Nanowires5.3.2 Template-Free Method Associated with A Deposition to Mono-Dispersed and Oriented Microspheres5.4 Electrical and Transport Properties of Conducting Polymer Nanostructures5.4.1 Room Temperature Conductivity5.4.2 Temperature Dependence of Conductivity5.4.3 Electrical Properties of A Single Micro/Nanostructure5.4.4 Magneto-Resistance5.5 Special Methods for Micro/Nanostructures of Conducting Polymers5.5.1 Aniline/Citric Acid Salts as The “Hard-Templates” for Brain-like Nanostructures5.5.2 Cu20 Crystal as A Hard Template5.5.3 Water-Assisted Fabrication of PANI-DBSA Honeycomb Structure5.5.4 Reversed Micro-Emulsion Polymerization5.6 Potential Applications of Conducting Polymer with Micro/Nanostructures5.6.1 Microwave Absorbing Materials5.6.2 EMI Shielding Materials5.6.3 Conducting Polymer Nanostructure-Based Sensors Guided by Reversible WettabilityReferencesAppendix Term Definitions