高等有机化学-双语版

本书特色

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本书第1章介绍了分子结构和化学键与反应活性的定性关系；第2章为立体化学，主要介绍了立体异构、消旋化合物的拆分、立体选择性和立体特异性反应、不对称合成等；第3章主要介绍有机反应的类型，通过举例来解释反应机理，并结合机理讨论反应中间体的结构、稳定性和化学性质；第4章讨论亲核取代反应的机理、立体化学和影响因素；第5章讨论加成和消除反应的机理和立体化学；第6章主要介绍羰基化合物的亲核加成反应；第7章介绍重排反应；第8章讨论芳香亲核和亲电取代反应，同时介绍定位效应；第9章介绍各类氧化和还原反应及歧化反应；第10章介绍周环反应。每章后附有相关习题、专业术语词汇表。为方便学生理解，每章后有中文列出的知识要点。
本书可供化学类专业高年级本科生和研究生使用，亦可供从事高等有机化学教学的教师参考。

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目录

chapter 1 chemical bonding and molecular structure 11.1 localized chemical bonding 11.2 dipole moments 31.3 inductive effects and field effects 31.4 delocalized chemical bonding 41.5 resonance structures drawn for conjugated structures 61.6 conjugative effect 71.7 hyperconjugative effect 81.8 steric effect 101.9 aromaticity and hückel’s rule 11problems 19vocabulary 20知识要点 21chapter 2 stereochemistry 262.1 enantiomers 272.2 resolution of racemates 362.3 the stereochemistry in reaction process 39problems 47vocabulary 48知识要点 49chapter 3 mechanisms of organic reactions 523.1 types of organic reactions 523.2 the variables of organic reactions 563.3 how do organic reactions occur: mechanisms 593.4 describing a reaction: intermediates 623.5 methods of determining mechanisms 68problems 70vocabulary 70知识要点 71chapter 4 nucleophilic substitution 744.1 mechanisms of nucleophilic substitutions 754.2 stereochemistry of nucleophilic substitutions 764.3 nucleophiles and nucleophilicity 774.4 the factors that can influence the rates of sn1, sn2 reactions 794.5 neighboring-group participation effect 82problems 85vocabulary 87知识要点 87chapter 5 addition and elimination reactions 915.1 electrophilic addition reactions 915.2 elimination reactions 965.3 elimination vs substitution 102problems 102vocabulary 104知识要点 105chapter 6 reactions of carbonyl compounds 1076.1 the nucleophilic addition reaction mechanisms 1076.2 the nucleophilic addition reactions to the carbonyl groups 1076.3 the addition and elimination reactions 1116.4 the reactivity and stereoselectivity of nucleophilic additions 1126.5 condensation reactions 1136.6 reaction with ylides 1206.7 the nucleophilic substitutions of carboxylic acid and their derivatives 121problems 124vocabulary 125知识要点 126chapter 7 rearrangements 1297.1 nucleophilic rearrangements 1297.2 electrophilic rearrangements 1407.3 rearrangements on aromatic rings 143problems 146vocabulary 147知识要点 148　　chapter 8 electrophilic and nucleophilic aromatic substitutions 1508.1 electrophilic aromatic substitution 1508.2 specific electrophilic aromatic substitution reactions 1518.3 directing effects of substituents 1588.4 effects of multiple substituents on electrophilic aromatic substitution 1598.5 nucleophilic aromatic substitution 160problems 164vocabulary 165知识要点 166chapter 9 oxidation and reduction reactions 1679.1 oxidation of alkenes and alkynes 1679.2 oxidation of alcohols 1699.3 oxidation of aldehydes and ketones 1739.4 oxidation of aromatic side chains and the aromatic rings 1759.5 reduction reactions 1759.6 other reduction reactions 1849.7 disproportionation reactions 187problems 188vocabulary 189知识要点 189　　chapter 10 pericyclic reactions 19310.1 electrocyclic ring opening/closure reactions 19310.2 cycloaddition reactions 19710.3 sigmatropic rearrangements 204problems 207vocabulary 209知识要点 209　　appendix ⅰ 《advanced organic chemistry》final test（1） 211appendix ⅱ 《advanced organic chemistry》final test（2） 216appendix ⅲ 《advanced organic chemistry》final test（3） 222参考文献 227

封面

书名:高等有机化学-双语版

作者:谢普会

页数:227

定价:¥35.0

出版社:化学工业出版社

出版日期:2015-03-01

ISBN:9787122224033

PDF电子书大小:120MB 高清扫描完整版